13.1 Catching Lizards
13.2 The Rate of a Chemical Reaction
13.3 The Rate Law: The Effect of Concentration on Reaction Rate
13.4 The Integrated Rate Law: The Dependence of Concentration on Time
13.5 The Effect of Temperature on Reaction Rate
13.6 Reaction Mechanisms
13.7 Catalysis
- Elementary Reactions and Mechanism
- Reaction profile of rate determining step
- What Potential Energy Curves Show
- Arrhenius Equation: Dependence of Rate Constant (k) on T
Rate constant (k)
k = A e-Ea/RT
A = frequency factor: A = p xz
Ea= Activation energy
R = gas constant
T = Kelvin temperature
p = collision factor
z = Orientation factor
- Orientation Factor: Some Unsuccessful Collisions
- Collision Model
- Effect of Concentration on Frequency of Bimolecular Collisions
- Transition State: Activated Complex or Reaction Intermediates
- Catalyst
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